日本ゼオライト学会 刊行物 Publication of Japan Zeolite Association

ISSN: 0918–7774
一般社団法人日本ゼオライト学会 Japan Zeolite Association
〒162-0801 東京都新宿区山吹町358-5 アカデミーセンター Japan Zeolite Association Academy Center, 358-5 Yamabuki-cho, Shinju-ku, Tokyo 162-0801, Japan
Zeolite News Letter 9(2): 49-59 (1992)
doi:10.20731/zeoraito.9.2.49

解説解説

新第三紀海成層中の沸石化作用と泥質岩の圧密Zeolitization and compaction of argillaceous rocks in Neogene marine sediments, Japan

三井石油開発株式会社技術部Mitsui Oil Exploration Co., Ltd.

発行日:1992年6月1日Published: June 1, 1992
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埋没続成下における泥質岩の圧密とアルカリ系沸石反応は共に脱水作用であり,岩石密度と比重が増加する。本邦の含油新第三系において,沸石帯の出現深度や層準に地域的差異があるのに対して,沸石帯上限の泥質岩孔隙率は一定である。孔隙率33%で珪質ガラスからクリノプチロル沸石へ,17%で方沸石へ,12%で曹長石へ転換する。また,沸石の比重は沸石帯上限の泥質岩密度にほぼ一致する。この相関性は圧密作用が沸石の転換にとって最高地層温度や被熱時間と同様に重要な規制要因であることを示す。堆積物の埋没過程で珪質ガラスや沸石は次第に周辺の堆積物と物理的に不均衡状態となり不安定な鉱物となる。そこで,間隙水と化学反応を起し,結晶水を放出すると共に鉱物比重を増して周辺の堆積物の密度と調和し,物理的平衡を保つ。

On the physical point of view, the zeolitization in the marine sediments during burial diagenesis is a kind of compaction phenomenon, such as the explusion of water and the increase in specific gravity. The zeolite zones in the Neogene marine sediments of the Japanese oil producing regions occur at various depth, and are oblique to the stratigraphic datums. But, the porosity of argillaceous rocks at the top of each zeolite zone is relatively constant: approximately 33% at the Zone II(clinoptilolite), 17% at the Zone III(analcime), and 12% at the Zone IV(albite). The specific gravity of zeolite is nearly equal to the bulk density of argillaceous rocks at the top of each zeolite zone.

The compaction of sediments is one of the important factors for the transformation of silicic glasses to clinoptilolite-analcime-albite reaction series, as same as maximum formation temperature and effective heating time. Silicic glasses or the existing zeolite are physically unstable mineral under the increasing overburden, and begin the transformation into high grade zeolite to keep with physical equilibrium in the surrounding sediments, as accompanied by the chemical exchanges of ions, the explusion of water and the increase of specific gravity.

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