日本ゼオライト学会　刊行物 Publication of Japan Zeolite Association

ISSN: 0918–7774
一般社団法人日本ゼオライト学会 Japan Zeolite Association
〒162-0801 東京都新宿区山吹町358-5 アカデミーセンター Japan Zeolite Association Academy Center, 358-5 Yamabuki-cho, Shinju-ku, Tokyo 162-0801, Japan
Zeolite News Letters 18(1): 10-18 (2001)
doi:10.20731/zeoraito.18.1.10

解説解説

A novel metbod for the preparation of a titanium and boron containing zeolitic material with MFI structure and its catalytic properties

Ulf Barsnick，Wolfgang F．HölderichUlf Barsnick, Wolfgang F．Hölderich

Department of Chemical Technology and Heterogeneous Catalysis, University of Technology ◇ RWTH Aachen Worringerweg 1, 52074 Aachen, Germany

発行日：2001年3月10日Published: March 10, 2001
PDF

A new straight forward method，for the preparation of a titanium and boron containing MFI type　zeolitic material is presented. Thereby the　use of sodium and HF are avoided. The Obtained material was characterized by XRD, 11B, 29Si and 1H → 29Si cross-poladzation MASNMR as well as ICP-AES, FT-IR and UV-Vis spectroscopies. This (Ti, B)-MFI zeolite crystallizes rapidly and contains less unwanted extra framework titanium than are reference material synthesized via a known route. Tests with respect to the catalytic properties showed, that this (Ti, B)-MFI zeolite is active in bifunctional catalysis. Phenylacetaldehyde was obtained via the liquid phase epoxidation of styrene followed by epoxide rearrangement of the "in-situ" formed styreneoxide．

© 2001 ゼオライト学会© 2001 Japan Association of Zeolite

This page was created on 2017-06-13T11:54:41.593+09:00
This page was last modified on

このサイトは（株）国際文献社によって運用されています。